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Clever
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binding sites proceeds following an allosteric mechanism with positive cooperativity ( Freye ACIE 2012 , JACS 2013 ). The exchange of larger anions for smaller ones in the outer two pockets leads to a [...] along the common Pd 4 -axis, thereby enlarging the central cavity ( Freye CEJ 2013 ; Dieterich PCCP 2012 ). In further work, we showed that this can be used to trigger recognition of small uncharged guest [...] ACIE 2018 ) ; c) huge Pd 8 L 16 catenane ( Bloch ACIE 2018 ); d) double-trefoil knot ( Engelhard ACIE 2012 ). In parallel, we started to equip monomeric and interpenetrated cages with functional backbones …